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衢州市(开化县、衢江区、常山县、江山市、柯城区、龙游县)









怒江傈僳族自治州(泸水市、福贡县、贡山独龙族怒族自治县、兰坪白族普米族自治县)









玉溪市(新平彝族傣族自治县、通海县、江川区、华宁县、澄江市、红塔区、易门县、元江哈尼族彝族傣族自治县、峨山彝族自治县)连云港市(赣榆区、东海县、灌云县、灌南县、海州区、连云区)









朝阳市(双塔区、龙城区、喀喇沁左翼蒙古族自治县、朝阳县、凌源市、建平县、北票市)  信阳市(光山县、潢川县、罗山县、商城县、浉河区、平桥区、淮滨县、固始县、息县、新县)









宁夏回族自治区









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大同市(新荣区、阳高县、灵丘县、广灵县、浑源县、天镇县、云冈区、左云县、云州区、平城区)武威市(古浪县、天祝藏族自治县、凉州区、民勤县)









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深圳市(龙华区、南山区、坪山区、龙岗区、宝安区、福田区、盐田区、罗湖区、光明区)

据悉,位于宁波巨化化工科技有限公司南厂区的15万吨/年特种聚酯新材料项目,占地40多亩的新项目厂房已拔地而起,设备已安装完毕。

宁波巨化董事长周强表示:“这个聚酯新材料项目是全球单体最大项目、省‘千项万亿’工程,总投资16.8亿元,计划上半年投产,达产后预计可新增年销售收入25亿元。这个项目将打破国外长期技术垄断,实现全产业链国产化。”

项目概况:

2023年7月4日,浙江省“千项万亿”重大项目集中开工活动举行,宁波巨化15万吨/年特种聚酯切片新材料项目开工。

项目名称:15万吨/年特种聚酯切片新材料项目

项目投资:约15.76亿元

建设性质:扩建

项目实施主体:宁波巨化化工科技有限公司

建设地点:宁波石化经济技术开发区跃进塘路501号,本项目不需新增用地,所有新增均在原有用地范围内建设

建设内容:南厂区主要建设内容有PDO装置、PTT装置、1,3-丙二醇罐区、PTT仓库、导热油炉、配电机柜间改造、南厂区装卸站台改造、控制室改造等。PDO装置、PTT装置、导热油炉、粗PDO罐区、乙醇储罐等在南厂区现有空地上新建。北厂区主要建设内容为环氧乙烷罐区、北厂区装卸站台改造等。新建从富德至北厂区的环氧乙烷外管(总长4.6km的不锈钢管)。

产品方案:7.2吨/年PDO(其中:商品量1.05万吨、中间产品6.15万/年)和15吨/年PTT的主装置及其配套工程

该项目PDO(1,3-丙二醇)生产采用环氧乙烷法制得,工艺分两步进行,首先是将环氧乙烷与合成气氢甲酰化生成3-羟基丙醛,再将3-羟基丙醛加氢生成PDO。该技术的优点在于:催化剂用量很低使其费用大幅度降低、转化率高、反应产物和催化剂容易分离、高沸点副产物很少、工艺先进、经济合理。

该项目PTT生产主要原料1,3-丙二醇由PDO(1,3-丙二醇)装置自供,采用钛系组份为催化剂,以二氧化钛作为消光剂,1,4-丁二醇为改性剂,精对苯二甲酸(PTA)和1,3-丙二醇(PDO)为原料经直接酯化脱水合成单体对苯二甲酸丙二醇酯(BHPT),再缩聚为产品聚对苯二甲酸丙二醇酯(PTT)。聚酯熔体生产线采用四釜流程,即两段酯化、预缩聚和终缩聚。该工艺从进料配置到切粒单元均为封闭系统,故产污节点较少,三废收集率高。

该项目主要原料为环氧乙烷、合成气、氢气及PTA。合成气来自四明化工,依托现有合成气输送管线;氢气来自中金石化,依托现有氢气输送管线;环氧乙烷来自镇海炼化/富德能源,来自镇海炼化的环氧乙烷通过槽车进行运输至北厂区暂存,新增从富德能源至巨化南厂区的环氧乙烷输送管线至北厂区暂存;中金石化PTA装置可就近供应PTT装置所需的另一主要单体PTA。

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